Firewall App Blocker 1.4Free
Prevents any application installed on your computer from connecting to your local area network or to the Internet. The tool includes drag-and-drop functionality as well as the option to block the connection for every program and whitelist only the ones that are allowed to access the Web.
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Firewall App Blocker is a free program that allows you to set the Windows Firewall to block or unblock certain applications. Just Drag and drop the application that you want to block or use the browse button to select it, and if you want to allow it again just use the delete button.